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Electronic Configurations and Examples -- A-level Chemistry


Electronic Configurations: The Blueprint of Atoms


Before we embark on our journey into subshells and atomic orbitals, let's revisit electronic configurations. Think of electronic configurations as a blueprint that outlines the arrangement of electrons within an atom. Understanding electronic configurations provides us with insights into an atom's behavior and properties.


Deciphering Subshells: The Building Blocks of Atoms


What Are Subshells?


Subshells are like the building blocks that construct the architecture of an atom. They are defined by the principal quantum number (n) and are further categorized based on their angular momentum quantum number (l).


Types of Subshells


  • s-Subshell: Spherical in shape, can hold a maximum of 2 electrons.

  • p-Subshell: Dumbbell -shaped, can hold a maximum of 6 electrons.

  • d-Subshell: Complex in shape, can hold a maximum of 10 electrons.

  • f-Subshell: Elaborate shape, can hold a maximum of 14 electrons.


Subshell Configuration Example


Let's consider the element Lithium (Li) with an atomic number of 3. The electronic configuration of Lithium is 1s²2s¹. This configuration signifies that Lithium has two electrons in the 1s subshell and one electron in the 2s subshell.


Subshells

Unveiling Atomic Orbitals: Electron's Address in an Atom


What Are Atomic Orbitals?


Atomic orbitals are regions within an atom where an electron is likely to be found. Each subshell is composed of one or more atomic orbitals, each of which can accommodate a specific number of electrons.


Types of Atomic Orbitals


  • s-Orbital: Spherical in shape, can hold a maximum of 2 electrons.

  • p-Orbitals: Dumbbell-shaped (px, py, pz), collectively can hold 6 electrons.

  • d-Orbitals: Four different shapes (dx²-y², dz², dxz, dyz), collectively can hold 10 electrons.

  • f-Orbitals: Seven different shapes, collectively can hold 14 electrons.


Atomic Orbital Configuration Example


Let's examine the element Oxygen (O) with an atomic number of 8. The electronic configuration of Oxygen is 1s²2s²2p⁴. This configuration indicates that Oxygen has two electrons in the 1s orbital, two in the 2s orbital, and four in the 2p orbital.


Atomic Orbitals

Putting It All Together: Visualization of Subshells and Atomic Orbitals


Visual Representation


To reinforce our understanding, let's visualize the arrangement of electrons in the subshells and atomic orbitals through an illustration:


Electron Arrangement


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